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Fig 1.

Structure of LA and some of its degradation products.

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Fig 1 Expand

Fig 2.

Schematic representation of experimental procedure.

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Fig 3.

Degraded Samples prepared using different methods.

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Table 1.

T1 values of monitored protons (tested at 293 K).

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Table 1 Expand

Table 2.

Experimental conditions and kinetic constants for LA degradation.

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Table 2 Expand

Fig 4.

280 nm UV chromatograms of degraded samples obtained under different initial pH values.

(a) Exp. No. II; (b) Exp. No. IV; (c) Exp. No. V.

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Fig 5.

Proposed degradation pathway for LA.

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Fig 6.

1H NMR spectra of LA.

(a) and degraded sample heating 5h in Exp. No. II (b).

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Fig 7.

Pesudo-first-order plots for degradation of LA at different experimental conditions.

()Exp. No. I; ()Exp. No. II; ()Exp. No.III; ()Exp. No. IV; ()Exp. No. V.

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Table 3.

Fitting results of Arrhenius equation.

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Table 3 Expand

Table 4.

Rate constants of Sal A at various experimental conditions.

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Table 4 Expand

Fig 8.

Concentration-time plots of Sal A at various experimental conditions.

()Exp. No. I; ()Exp. No. II; ()Exp. No.III; ()Exp. No. IV; ()Exp. No. V.

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