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Fig 1.

The targeted system of the present work contains two identical nanodroplets with a diameter of 8 nm.

Two droplets are put into a vacuum environment with a separated distance of 6 nm.

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Fig 1 Expand

Fig 2.

(a) Experimental results of impacting droplet with 20 μm upon a superhydrophobic solid surface.

(b) Sequential images of impingement of a nanodroplet with diameter of 8 nm from MD simulations.

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Fig 2 Expand

Fig 3.

(a) Impingement of binary nanodroplets with Dsep = 6 nm at We = 1.21 (b) The corresponding variation of mass center of each nanodroplet over impingement.

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Fig 3 Expand

Fig 4.

(a) Free evolution of impingement of binary nanodroplets at We = 30.18 and (b) corresponding variation of mass center of two droplets as a function of time.

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Fig 4 Expand

Fig 5.

Free evolution of unstable dynamics of the targeted system at (a) We = 120.8 and (b) We = 146.08.

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Fig 5 Expand

Fig 6.

Variation of dimensionless spreading factors of targeted systems as a function of time at (a) We = 1.21 and (b) We = 30.18.

(c) The evolution ofdroplets’ collision with Dsep = 6 nm, 12 nm, and 18 nm at We = 30.18.

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Fig 6 Expand

Fig 7.

(a) Variation of h* as a function of We at different values of Dsep.

(b) Phase diagram containing irrelevant and suppressive secondary spreading regimes with respect to Dsep and We.

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Fig 7 Expand

Fig 8.

(a) Variation of βpri, maxand βsec, max at various Dsep as a function of We1/2Re1/5.

The free evolution of impacting binary nanodroplets at We = 77.31 under (b) Dsep = 6 nm and (c) Dsep = 18 nm. (d) The proportion of energy dissipation at We = 77.31 and Dsep = 6 nm and 18 nm.

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Fig 8 Expand

Fig 9.

The collision of separated nanodroplets after the below droplet completely bounces off from solid surface at We = 42.65.

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Fig 9 Expand

Fig 10.

(a) Variation of tc on superhydrophobic solid surface under different given conditions.

(b) Evolution of impacting binary droplets at We = 118.2.

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Fig 10 Expand