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Fig 1.

Structural representation of a pre-cracked T4,4,4-graphyne nanosheet.

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Fig 1 Expand

Fig 2.

Stress–strain response of a pristine T4,4,4-graphyne nanosheet (150 Å × 150 Å) under uniaxial tension along the X-direction at different strain rates.

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Fig 2 Expand

Fig 3.

Fracture evolution of T4,4,4-graphyne nanosheets (150 Å × 150 Å) under uniaxial tension: (a) pristine X-loading, (b) pristine Y-loading, (c) pre-cracked X-loading, and (d) pre-cracked Y-loading.

Pre-cracks (40 Å) are introduced perpendicular to the loading axis.

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Fig 3 Expand

Fig 4.

Young’s modulus of pre-cracked T4,4,4-graphyne nanosheets under uniaxial loading at 300 K as a function of crack length in the X- and Y-directions.

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Fig 4 Expand

Fig 5.

Comparative variation of elastic modulus with crack length in T4,4,4-graphyne nanosheets under uniaxial loading: (a) X-direction and (b) Y-direction, predicted using AIREBO-M, REBO, and Tersoff potentials.

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Fig 5 Expand

Fig 6.

Ultimate tensile strength and fracture strain of pre-cracked T4,4,4-graphyne nanosheets with increasing central crack length (perpendicular to loading) under uniaxial tension in the X- and Y-directions.

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Fig 6 Expand

Fig 7.

Toughness of pre-cracked T4,4,4-graphyne nanosheets with increasing central crack length under uniaxial tension in the X- and Y-directions.

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Fig 7 Expand

Fig 8.

Mode I fracture toughness of pre-cracked T4,4,4-graphyne nanosheets with increasing central crack length under Mode I uniaxial loading.

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Fig 8 Expand

Fig 9.

Elastic modulus of pre-cracked T4,4,4-graphyne nanosheets as a function of crack orientation angle.

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Fig 9 Expand

Fig 10.

Angular dependence of ultimate strength and fracture strain of pre-cracked T4,4,4-graphyne.

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Fig 10 Expand

Fig 11.

Toughness of pre-cracked T4,4,4-graphyne nanosheets as a function of crack orientation angle.

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Fig 11 Expand

Fig 12.

Fracture toughness of pre-cracked T4,4,4-graphyne nanosheets with a 40 Å crack as a function of crack orientation angle.

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Fig 12 Expand

Fig 13.

Temperature dependence of the elastic modulus of a pre-cracked T4,4,4-graphyne nanosheet.

The data are fitted using the Wachtman equation, showing nearly linear thermal softening and directional anisotropy.

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Fig 13 Expand

Fig 14.

Ultimate stress and fracture strain of a pre-cracked T4,4,4-graphyne nanosheet.

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Fig 14 Expand

Fig 15.

Temperature-dependent variation of toughness for a pre-cracked T4,4,4-graphyne nanosheet.

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Fig 15 Expand

Fig 16.

Temperature-dependent variation of mode I fracture toughness for a pre-cracked T4,4,4-graphyne nanosheet.

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Fig 16 Expand