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Fig 1.

The studied river, stream gage location, and population points in the river basin (background terrain map was used from Natural Earth public domain http://www.naturalearthdata.com).

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Table 1.

Sampling stations and geographical locations on Gamasiab River, Iran.

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Table 2.

Adsorbents modified using different solutions.

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Fig 2.

Process overview of nano zeolite purification test process and design expert model.

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Fig 3.

Changes of sulfate along the Gamasiab river.

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Fig 4.

Changes of nitrate along the Gamasiab river.

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Fig 5.

Changes in phosphate along the Gamasiab river.

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Fig 6.

Changes in iron along the Gamasiab river.

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Fig 7.

Amount of sulfate after and before purification.

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Fig 8.

Adsorption rate by time.

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Fig 9.

Results of removing sulfate and phosphate interactions.

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Fig 10.

Sulfate and nitrate interaction.

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Fig 11.

Sulfate and iron interaction.

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Table 3.

Experiment design levels and factors for zeolite.

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Table 4.

Design matrix and laboratory data for effective factors in removing sulfate by zeolite (%).

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Table 5.

Results of ANOVA for the second-order model of sulfate removal by zeolite from laboratory data.

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Table 6.

Validation results of multi-response optimization endpoints for sulfate removal by zeolite.

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Fig 12.

Real and predicted data for zeolite.

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Fig 13.

Disturbance curves of the effect of main parameters on sulfate removal by zeolite.

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Fig 14.

Effect of pH and D/C on sulfate removal percentage by zeolite in the balance curve diagram.

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Fig 15.

Three-dimensional (3D) diagram of sulfate ion removal percentage by zeolite by surface response method and influencing factors of pH and D/C.

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Table 7.

Optimal maximum sulfate removal by zeolite points predicted in the software.

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Fig 16.

Langmuir model for sulfate adsorption process by zeolite.

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Fig 17.

Freundlich model for sulfate adsorption process by zeolite.

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