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Fig 1.

Distribution of sampling points in the tailing pond of the Qingshan lead-zinc mine.

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Table 1.

Heavy metal detection methods and instruments.

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Fig 2.

XRD pattern of the Pb‒Zn tailings.

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Fig 3.

SEM image of the lead-zinc tailings.

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Table 2.

Physical and chemical properties of tailing samples at each depth of profile.

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Table 3.

Statistical results of the total heavy metals in the soil around the Qingshan lead-zinc mine.

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Fig 4.

Proportion of chemical forms of heavy metals in soils.

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Table 4.

Concentrations of heavy metals in agricultural soils around a tailing pond from 2008–2016 (mg/kg).

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Fig 5.

Smoothed number of heavy metal concentration indices in agricultural land near mine tailing dams (2008–2016).

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Fig 6.

Smoothing values of the soil heavy metal concentration indices at different times.

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Fig 7.

Prediction of soil lead concentration under different smoothing coefficients.

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Fig 8.

Error analysis of the Pb concentration with different smoothing coefficients.

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