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Table 1.

Alloy compositions as tested via ICPAES.

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Fig 1.

Alloy cut used for testing.

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Fig 1 Expand

Fig 2.

Electrode prepared from cut metal sample.

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Table 2.

Composition of artificial seawater.

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Table 2 Expand

Fig 3.

Change in solution pH over time (with insert at higher resolution).

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Fig 3 Expand

Fig 4.

OCP data over 14 days.

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Fig 5.

Enumerated cell density on each alloy after 24 hrs of immersion.

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Fig 5 Expand

Fig 6.

SEM surfaces of bacterial adhesion after 7 and 14 days.

(a) Alloy A1 after 7 days (b) Alloy A1 after 14 days (c) Alloy A2 after 7 Days (d) Alloy A2 after 14 days (e)Alloy M1 after 7 days (f) Alloy M1 after 14 days.

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Fig 6 Expand

Fig 7.

SEM surfaces under as deposited and post-corrosion states.

(a) As-Deposited Surface of Alloy M1 (b) Post-Corrosion Surface of Alloy M1 after 14 Days Biotic Conditions (c) As-Deposited Surface of Alloy A1 (d) Post-Corrosion Surface of Alloy A1 after 14 Days Biotic Conditions (e) As-Deposited Surface of Alloy A2 (f) Post-Corrosion Surface of Alloy A2 after 14 Days Biotic Conditions.

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Fig 7 Expand

Table 3.

Enumerated pits on the surface of corroded alloys post-14 days in biotic conditions.

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Table 3 Expand

Fig 8.

Abiotic post-day 14 corrosion of Alloy M1.

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Fig 8 Expand

Fig 9.

Abiotic post-day 14 corrosion of Alloy A1.

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Fig 9 Expand

Fig 10.

Abiotic post-day 14 corrosion of Alloy A2.

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Fig 10 Expand

Fig 11.

Equivalent circuit model of Abiotic system in the study.

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Fig 11 Expand

Fig 12.

Alternative equivalent circuit model of Biotic system in the study.

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Fig 12 Expand

Fig 13.

Nyquist plots.

(a) Alloy A1 (b) Alloy A2 (c) Alloy M1 and (d) Corrosion resistance parameter of alloys.

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Fig 13 Expand

Fig 14.

Bode plots with Zmod.

(a) On Day 7 (b) On Day 14 biotic conditions.

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Fig 14 Expand

Fig 15.

Bode plot–phase angle Vs frequency.

(a) On Day 7 (b) On Day 14 biotic conditions.

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Fig 16.

Bode plot (Zmod vs Freq) for day 14 Biotic vs Abiotic conditions.

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Fig 16 Expand

Table 4.

Electrochemical impedance parameters obtained with abiotic conditions.

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Table 4 Expand

Table 5.

Electrochemical impedance parameters obtained with biotic conditions.

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Table 5 Expand

Fig 17.

Proposed transfer mechanism for Alloys A1 and A2.

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