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Fig 1.

Experimental flowchart.

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Fig 1 Expand

Fig 2.

The physical appearance of (a) TPC (b) PPC.

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Table 1.

Properties of base bitumen (VG30).

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Table 1 Expand

Fig 3.

(a) RTFO device used for simulation of short-term aging, and (b) PAV device used for simulation of long-term aging.

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Fig 4.

Frequency sweep result at 10 rad/s (a) G* (b) δ.

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Fig 5.

Aging index based on G* under (a) short-term aging, and (b) long-term aging.

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Fig 6.

Aging index based on δ under (a) RTFO and (b) PAV.

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Fig 7.

ZSV results at 60°C.

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Fig 8.

Aging index based on ZSV.

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Fig 9.

MSCR Jnr result at 60°C.

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Fig 10.

Aging index based on MSCR Jnr.

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Fig 11.

BYET results at 15 and 25°C.

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Fig 12.

FTIR spectra under different aging state (a) Control (b) TPCMA (c) PPCMA.

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Fig 13.

Carbonyl index under different aging states.

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Fig 14.

Sulfoxide index under different aging states.

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Fig 15.

1H-NMR spectra under different aging states (a) Control (b) TPCMA (c) PPCMA.

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Table 2.

Proton assignment in 1H-NMR [47,48].

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Table 2 Expand

Fig 16.

Har results.

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Fig 17.

Hγ results.

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Fig 18.

Correlation between MSCR Jnr and Hγ.

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