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Fig 1.

Archaeological information of the Qiaotou site.

(a) Location of Qiaotou, base map modified from USGS National Map Viewer (http://viewer.nationalmap.gov/viewer/); (b) Cultural history and rice domestication in the Lower Yangtze Valley; (c) Calibrated 2σ probability distribution of AMS Radiocarbon dates on wood charcoal from Qiaotou (Peking University AMS Laboratory, calibrated by Oxcal v 4.42).

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Fig 2.

Archaeological features from Qiaotou platform mound.

(a) Human burial 1(M44);b, The locations of human burials and associated pottery pits; (c) and (d) Painted pottery vessels suitable for serving foods and drinks; (e) A bird view photograph showing the location of the platform in relation to the ditch; (f) Pit H98 during excavation, which contained 50 complete pots; (g) A group of postholes from the eastern side of the platform; (h) and (i) Postholes with stone pillar bases; (j) The ditch (left) and platform (right) at Qiaotou.

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Fig 3.

Representative pottery types recovered from Qiaotou.

(a) and (b) Long-necked hu vessel; (c) Bowl; (d) Jar; (e) A selection of painted patterns from Qiaotou pottery.

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Fig 4.

Starch granules from Qiaotou pots compared with rice brewing experiment samples.

Qiaotou samples: (a) Qiaotou Type I starch (rice), compared with (b); (c) and (e) Compound rice starch granules showing central pitting (pointed by red arrows) and gelatinization (starch damage type 1), compared with (d) and (f); (g) Slightly gelatinized rice granules without pitting (starch damage type 2), compared with (h); (i) A gelatinized starch granule from Qiaotou, possibly from a USO (starch damage type 2); (j) A gelatinized starch granule from Qiaotou (starch damage type 2). Rice fermentation experiment samples: (b) A cluster of unmodified rice (Oryza sativa) starch granules; (c) and (f) Compound rice starch granules showing central pitting (pointed by red arrows) and gelatinization, a result of the combined effects of heating and enzymatic hydrolysis during the fermentation process; (h) Slightly gelatinized rice starch granules, showing faint extinction crosses under polarized light. Starch granules in c, e, f, h, i, and j are stained with Congo Red. They are stained red under in bright field light, with an orange-red glow in polarized light, indicating gelatinization. Each starch granule/compound is shown in bright field and polarized views (scale bars: 20 μm).

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Fig 4 Expand

Fig 5.

Starch remains from Qiaotou pottery compared with modern references.

(a) Qiaotou Type II starch (Job’s tears); (b) Job’s tears (Coix lacryma-jobi, from Yunnan); (c) and (d) Qiaotou Type III starch (Unidentified USOs); (e) Qiaotou Type IV starch (acorn); (f) Acorn (Quercus fabri, from Zhejiang). Each starch granule/compound is shown in bright field and polarized views.

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Fig 5 Expand

Table 1.

Starch data from Qiaotou.

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Table 1 Expand

Table 2.

Fungal elements from Qiaotou pottery and control samples.

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Table 2 Expand

Fig 6.

Molds and yeast cells from Qiaotou pottery compared with modern references.

Qiaotou samples: (a) Vesicle/sporangia without phialides/spores attached, compared with Aspergillus oryzae in (f); (b) Black sporangia connecting to sporangiophores, compared with Rhizopus in (g); (c) Rhizopus sporangiophore, compared with (h); (d) Vesicle/sporangia without phialides/spores attached, compared with Aspergillus oryzae in (i); (e) Yeast cells in budding process, compared with (j); Modern samples: (f) A. oryzae vesicle; (g) Rhizopus rhizoids, sporangiophore, sporangia and sporangiospores; (h) Rhizopus rhizoids; (i) A. oryzae mycelium; (j) Cultured, domesticated S. cerevisiae yeast in various budding forms (scale bars: 20 μm).

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Fig 7.

Phytolith remains from Qiaotou pottery.

(a) Double peak (Oryza, rice husk); (b) elongate skeletons (Poaceae); (c) Oryza-type bulliform (Oryza, rice leaf/stem); (d) Parallel scooped bilobate (Ehrhartoideae); (f) Cross (cf. Job’s tears); (g) Rondel (Poaceae); (h) Articulated quadrilobate (Panicoideae) (i) Crenate elongate skeleton (cf. Poaceae husk).

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Fig 8.

Quantitative summary of Qiaotou microfossil residue and control samples.

(a) Comparison of microfossil quantities from Qiaotou residue and control samples; (b) Summary of microfossil residues from Qiaotou pottery.

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Fig 9.

Beer-related microfossil remains.

(a) Rice starch granules; (b) A starch granule from an unidentified USO; (c) A starch granule from Job’s tears, showing a characteristic Z-shaped arm; (d) A double-peak phytolith from rice husk; (e) Yeast cells in budding process; (f) and (g) vesicle/sporangia without phialides/spores attached, compared with Aspergillus oryzae in Fig 6; (h) Black sporangia connecting to sporangiophores, compared with Rhizopus in Fig 6 (scale bars: 20 μm).

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