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Fig 1.

Molecular structures of organic molybdenum given by the suppliers.

(a) molybdenum dithiocarbamate (MoDTC), (b) molybdenum amide (MA), and (c) Molybdenum dialkyldithiophosphate (MoDDP).

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Fig 1 Expand

Table 1.

Base oil and additive abbreviations.

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Table 1 Expand

Table 2.

Test oil formulations.

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Table 2 Expand

Fig 2.

The ring and block of test specimens.

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Fig 2 Expand

Fig 3.

Schematic of test rig.

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Fig 3 Expand

Fig 4.

Photos of test rig.

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Fig 4 Expand

Fig 5.

The base oil viscosity in different test temperature.

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Fig 5 Expand

Table 3.

The friction test conditions.

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Table 3 Expand

Fig 6.

Shows the friction coefficient of test lubricant containing MoDTC and organic friction modifiers during 6 hours test, test temperature 40°C.

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Fig 6 Expand

Fig 7.

Influence of organic friction modifiers to the friction coefficient of organic molybdenum, (a) MoDTC and organic friction modifiers, (b) MA and organic friction modifiers, (c) MoDDP and organic friction modifiers.

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Fig 7 Expand

Fig 8.

Optical images of block wear surface.

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Fig 8 Expand

Fig 9.

Wear scar width of block lubricated with different test oil formulas at 150°C.

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Fig 9 Expand

Fig 10.

SEM image of wear surface.

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Fig 10 Expand

Fig 11.

EDS of friction surfaces (a) MoDTC (MC) containing lubricants, (b) molybdenum amide (MA) containing lubricants, (c) MoDDP (MP) containing lubricants, (d) Base oil (BO).

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Fig 11 Expand

Fig 12.

Friction surface XPS photopeaks of Mo3d lubricated with MoDTC (MC) containing lubricants.

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Fig 12 Expand

Fig 13.

Friction surface XPS photopeaks of Mo3d lubricated with Molybdenum Amide (MA) containing lubricants.

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Fig 14.

The XPS photopeaks of Mo3d lubricated with MoDDP (MP) containing lubricants.

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Fig 14 Expand