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Table 1.

Optimized parameters of the F-ASS technique.

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Table 1 Expand

Table 2.

Validation parameters of the analytical method using the F-AAS technique.

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Table 2 Expand

Table 3.

Optimized time-temperature parameters in the GF-AAS technique.

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Table 3 Expand

Table 4.

Validation parameters of the analytical method using the GF-AAS technique.

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Table 4 Expand

Fig 1.

Distributions of daily sap volume depending on sap collection date (I-III) for young and old trees (box: 25th percentile (Q1), median and 75th percentile (Q3); whiskers: min. value within Q1-1,5*IQR and max value within Q3+1,5*IQR, circles: outliers).

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Fig 1 Expand

Table 5.

Summary statistics for daily sap volume (dm3/24h).

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Table 5 Expand

Fig 2.

Distributions of the contents of minerals in birch sap for young and old trees depending on the sap collection date (box: 25th percentile (Q1), median and 75th percentile (Q3); whiskers: min. value within Q1-1,5*IQR and max value within Q3+1,5*IQR).

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Fig 2 Expand

Fig 3.

Distributions of the contents of heavy metals in birch sap for young and old trees depending on the sap collection date (box: 25th percentile (Q1), median and 75th percentile (Q3); whiskers: min. value within Q1-1,5*IQR and max value within Q3+1,5*IQR).

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Fig 3 Expand

Table 6.

Summary statistics for the content of minerals in birch sap (mg/dm3).

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Table 6 Expand

Table 7.

Summary statistics for the content of heavy metals in birch sap (μg/dm3).

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Table 7 Expand

Fig 4.

Effect of different factors on the content of minerals in birch sap.

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Fig 4 Expand

Table 8.

Prediction of the content of minerals in birch sap by the GLM (mg/dm3).

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Table 8 Expand

Table 9.

Prediction of the content of heavy metals in birch sap by the GLM (μg/dm3).

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Table 9 Expand

Fig 5.

Effect of different factors on the content of heavy metals in birch sap.

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Fig 5 Expand

Fig 6.

Implementation of daily dietary reference values (as recommended by EFSA for an adult woman) by one liter of birch sap obtained by combining the birch sap from 6 trees of one age group on successive collection dates.

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Fig 6 Expand

Fig 7.

Concentration of heavy metals in birch sap obtained by combining the birch sap collected from 6 trees of one age group on successive collection dates, referenced to the parametric values for drinking water (horizontal line: guideline values for chemicals that are of health significance in drinking-water).

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Fig 7 Expand