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Fig 1.

Representative IR raw (panel A) and Savitzky-Golay first derivative transformed spectra (panel B) of vaginally inserted swabs, control-dry (rayon swabs), control–water (rayon dipped in water) and control-VSF (rayon dipped in vaginal fluid simulant).

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Fig 1 Expand

Fig 2.

PCA score plots showing separation of vaginally inserted swabs and various control swab conditions (dry, or treated with water or VFS) using raw spectra (panel A), IR region of 1740–1140 cm-1(panel B), and IR region of 1685–1485 cm-1(panel C).

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Fig 2 Expand

Table 1.

Summary of classification models developed for identification of vaginal swabs.

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Table 1 Expand

Fig 3.

Representative raw infrared spectra (panel A) and Savitzky-Golay first derivative transformed spectra (panel B) of vaginal swabs, vaginal swabs + semen and rayon + semen.

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Fig 3 Expand

Table 2.

Summary of classification models tested at 5% significance level for identification of vaginal swabs (baseline) from vaginal swabs containing semen and rayon swabs containing semen only.

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Table 2 Expand

Table 3.

Summary of classification models developed for identification of vaginal swabs containing HEC placebo gel tested at 5% significance level.

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Table 3 Expand

Fig 4.

Raw spectra(4000–650 cm-1) of vaginal swabs (baseline, no placebo insert) and vaginal swabs containing placebo insert.

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Table 4.

FTIR predictions summary for placebo insert study (CONRAD D15-134).

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Table 4 Expand

Fig 5.

TFV API spectra profile and its corresponding functional peaks in spectra of TFV gel and insert formulations.

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Fig 5 Expand

Table 5.

Validation of discriminant models developed for identification of vaginal swabs (baseline) and vaginal swabs containing placebo or TFV active inserts.

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Table 5 Expand