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Table 1.

Formula symbols.

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Fig 1.

Random search spaces for false positive matches.

To model matches where one correct and one incorrect partner are combined requires considering a linear random match space (A). In contrast, when modelling matches with two incorrect partners it requires construction of a quadratic random match space depending on whether the cross-linker is homodimeric, non-directional (B), homodimeric, directional (C), heterodimeric, non-directional (D), or heterodimeric, directional (E).

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Fig 2.

Maximal error from using formula 1.

Maximal expected error when using formula 1, exemplified for the extreme case of every possible combination of links being observed. X-axis is the size of the database and Y-axis is the maximal error. The green and blue line give the border cases of 0% overlap for both sides of the cross-linker and 100% overlap respectively. The gray area represents possible errors for all cross-linker with partial overlap. Residue-level for HSA cross-linked SDA (dark red dot) and HSA cross-linked with EDC (light red dot) are given as reference.

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Table 2.

Examples of maximal expected error when using the simple formula for HSA, cross-linked with either EDC or SDA.

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