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Fig 1.

Schematic of lithium ion battery electrochemical model.

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Fig 1 Expand

Table 1.

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Table 1 Expand

Table 2.

Equations for the electrochemical model.

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Table 2 Expand

Table 3.

The variables in the electrochemical model.

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Table 3 Expand

Table 4.

The physical parameters in the electrochemical model.

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Table 4 Expand

Fig 2.

The experiment scene of the battery discharging.

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Fig 2 Expand

Fig 3.

Comparison of simulated results of working voltage with experimental data during different discharge rate (1/3 C, 1C, and 4 C) under 25°C.

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Fig 3 Expand

Fig 4.

Comparison of simulated results of working voltage with experimental data during different ambient temperature (0°C, 25°C, and 35°C) under 1C discharge rate.

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Fig 4 Expand

Fig 5.

Li ion concentration at center (c_c) and surface (c_s) of active material particles across electrode with different discharging time (0s, 900s and 1800s) at 1C discharging rate.

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Fig 5 Expand

Table 5.

The maximum, minimum and average Li-ion concentration at the surface of electrode with different shelve time.

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Table 5 Expand

Fig 6.

Distribution of electrolyte salt concentration for the 1C discharging.

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Fig 6 Expand

Fig 7.

Comparison of simulated results of working voltage during different particle radius.

(a) positive electrode, (b) negative electrode.

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Fig 7 Expand

Fig 8.

Li-ion concentration at center (c0) and surface (cr) of active material particles across electrode with different active material particle sizes.

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Fig 8 Expand

Fig 9.

Li-ion concentration at surface of negative active particles across electrode of batteries with different electrode thickness.

(a) negative electrode, (b) positive electrode.

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Fig 9 Expand

Table 6.

The Li-ion concentration at surface of negative active particles across electrode of batteries with different electrode thickness relaxed 0, 100, 200s after discharging 1C for 1800s.

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Table 6 Expand