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Fig 1.

Schematics of the experimental design.

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Fig 2.

Representative culture plates of MRSA.

(A) Control I. (B) Control II. (C) Triclocarban-treated sample. (D) Representative plate showing no bacterial growth from samples treated with either Ethanol, Isopropanol, Sodium hypochlorite or Triclosan.

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Fig 3.

PCA-LDA scores and loadings plot from comparison of the ethanol-treated, isopropanol-treated, sodium-hypochlorite-treated, triclosan-treated and triclocarban-treated spectra.

A) Three-dimensional scores plot of IR spectra from all treated-MRSA groups, which clearly show the separation of spectra. Each point in the scatter plot represents a pixel IR spectrum (an area of 1.1×1.1μm2). B) Corresponding cluster vector plot for each treatment showing the discriminatory features in the spectral region between 1800 and 900 cm-1, responsible for the separation of spectra; i.e. triclocarban-treated (yellow); triclosan-treated (black); sodium hypochlorite-treated (red); isopropanol-treated (blue) and ethanol-treated (green), respectively. Nearly 10,000 IR spectra were derived from each group for the comparison.

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Table 1.

Discriminatory frequencies (cm-1) of the ethanol-treated, isopropanol-treated, sodium hypochlorite-treated, triclosan-treated and triclocarban-treated MRSA derived from PCA-LDA.

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Fig 4.

Comparison of the ethanol-treated and isopropanol-treated MRSA vs. control groups.

A,B) Average IR spectra from control I (purple), control II (pink), ethanol-treated (green) and isopropanol-treated (blue) MRSA. The spectra were averaged over nearly 40,000 individual IR spectra (64×64 pixels; 4096 spectra per measurement, 10 measurement per sample). C,D) Two-dimensional scores plot from PCA-LDA analysis (LD-2 vs. LD-1) derived from the comparison between control I, control II and ethanol-treated spectra (C) and between the controls and isopropanol-treated spectra (D). E,F) Corresponding cluster vector plot for the comparison made in C,D and the vector plot per cluster showing the significant discriminatory features, is shown.

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Table 2.

Discriminatory frequencies (cm-1) of the comparison between ethanol-treated and isopropanol-treated, with control groups of MRSA derived from PCA-LDA.

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Table 2 Expand

Fig 5.

Comparison of the sodium hypochlorite-treated, triclosan-treated and triclocarban-treated spectra vs. control I and control II groups.

A,B,C) Average IR spectra from control I (purple), control II (pink), sodium hypochlorite-treated (red), triclosan-treated (black) and triclocarban-treated (yellow) MRSA. The spectra were averaged over nearly 40,000 individual IR spectra in each case. D,E,F) Two-dimensional scores plot from PCA-LDA analysis (LD-2 vs. LD-1) derived from the comparison of control I, control II and sodium hypochlorite-treated (D), triclosan-treated (E) and triclocarban-treated (F). G,H,I) Corresponding cluster vector plot for the comparison made in D, E and F and the vector plot per cluster highlighting the significant discriminatory features, is demonstrated.

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Fig 5 Expand

Table 3.

Discriminatory frequencies (cm-1) of the comparison between sodium hypochlorite-treated, triclosan-treated and triclocarban-treated, and control groups of MRSA derived from PCA-LDA.

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Table 3 Expand