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Fig 1.

Diagrammatic representation of animal immunization protocol.

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Fig 1 Expand

Fig 2.

FTIR spectra of (a) native HSA (b) HSA modified with 400 mg/dL of glucose.

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Fig 2 Expand

Fig 3.

Mass spectroscopic profile of (a) native HSA (b) standard carboxymethyl lysine (c) HSA+100 mg/dL glucose (d) HSA+200 mg/dL glucose (e) HSA+300 mg/dL glucose (f) HSA+400 mg/dL glucose.

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Table 1.

Heamtological and rectal temperature analysis of preimmune and immune rabbits demonstrating the inflammatory response after immunization with glycated HSA (antigen).

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Table 1 Expand

Table 2.

Biochemical analysis of preimmune and immune rabbits after immunization with glycated HSA (antigen).

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Table 2 Expand

Fig 4.

(a) Level of induced antibodies against native HSA. Direct binding ELISA of native HSA with pre-immune and immune sera. The microtitre plates were coated with native HSA (10 μg/mL). (b) Level of induced antibodies against glucose modified HSA. Direct binding ELISA of glucose modified HSA with pre-immune and immune sera. The microtitre plates were coated with native HSA (10 μg/mL).

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Fig 5.

(a) Inhibition ELISA of anti-HSA immune and pre-immune sera with native HSA. Microtitre plates were coated with native HSA (10 μg/mL). (b) Inhibition ELISA of anti-glucose-HSA immune and pre-immune sera with glucose modified HSA. Microtitre plates were coated with native HSA (10 μg/mL).

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Fig 5 Expand

Fig 6.

(a) Binding of affinity purified anti-HSA IgG and pre-immune IgG to native HSA. Microtitre plates were coated with native HSA (10 μg/mL). (b) Binding of affinity purified anti-glucose modified-HSA IgG and pre-immune IgGto glucose modified- HSA. Microtitre plates were coated with glucose modified- HSA(10 μg/mL).

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Fig 6 Expand

Fig 7.

(a) Inhibition of binding of affinity purified anti-HSA IgG and pre-imune IgG to native HSA. Microtitre plates were coated with native HSA (10 μg/mL). (b) Inhibition of binding of affinity purified anti-glucose-HSA IgG and pre-imune IgG to glucose modified HSA. Microtitre plates were coated with native HSA (10 μg/mL).

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Fig 7 Expand

Fig 8.

Direct binding ELISA of serum auto-antibodies in (a) T2DM (n = 50) (c) T1DM (n = 50) (e) GDM (n = 50) (g) T2DM+CKD (n = 50) with native and 400 mg/dL glucose modified HSA and normal human sera (NHS) served as control in (b) (n = 50), (d) (n = 50), (f) (n = 50) and (h) (n = 50).

The plate was coated with the respective antigens (10μg/mL). A p value <0.05 considered to be significant. ns = non-significant

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Fig 8 Expand

Fig 9.

(a) Ultraviolet absorption spectra of native HSA+IgG immune complex and AGEs HSA+IgG immune complex with 400 mg/dL D-glucose.

Fluorescence emission profile of immune complex (native HSA+IgG) shown by black colour and immune complex (AGE-HSA+IgG) shown by red colour.

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Fig 10.

X-ray diffraction pattern under scan range of 10–500 (a) affinity purified IgG alone (b) immune complex of native HSA with IgG (c) immune complex of AGE-HSA (modified with 400 mg/dL D-glucose) with IgG.

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Fig 10 Expand