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Fig 1.

Schematic description of denaturation of proteins by surfactant.

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Fig 2.

The diffusion coefficient for the β-lactoglobulin-SDS (A), transferrin-SDS (B) and human insulin-SDS (C) complexes as a function of SDS concentration determined using the Taylor dispersion analysis.

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Fig 3.

ECD spectra showing changes in the tertiary structure of β-lactoglobulin (A), transferrin (B) and human insulin (C) with increasing surfactant concentration. For β-lactoglobulin and transferrin the concentrations of SDS were 4.3 x 10−4 M and 8.7 x 10−2 M for partially and fully denatured protein, respectively. For insulin the concentrations of SDS were 2.3 x 10−4 M and 8.7 x 10−2 M for partially and fully denatured protein, respectively.

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Table 1.

The ratio of the number of micelles to the number of proteins.

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Table 2.

Comparison of diffusion coefficients determined using the Taylor dispersion analysis and dynamic light scattering before and after addition of SDS at high concentration to the solution.

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Table 2 Expand