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Fig 1.

Reaction of 2-aminoquinolin-4(1H)-one with primary and secondary amines.

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Fig 2.

Plausible mechanism of the reaction yielding tetrahydropyrimido[4,5-b]quinolin-5-ones 5.

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Fig 2 Expand

Fig 3.

Plausible mechanism of the reaction yielding pyrimido[4,5-b]quinolin-3-ium salt 4.

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Fig 3 Expand

Fig 4.

Transformation of 2-aminoquinolin-4(1H)-one and Mannich products 2 to bis and tris-quinolinone derivatives.

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Fig 4 Expand

Fig 5.

Plausible mechanism leading to derivatives 3 and 6.

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Fig 5 Expand

Fig 6.

Reaction of Mannich product 2a with indole and thiophenol.

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Fig 6 Expand

Fig 7.

ORTEP view of compounds 2b and 5a.

Displacement ellipsoids are drawn at the 50% probability level.

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Fig 7 Expand