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Table 1.

Study groups and fabricated biphasic calcium phosphate scaffolds ratios.

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Table 1 Expand

Table 2.

Fluid characteristics of binder solution.

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Table 2 Expand

Fig 1.

Characteristics of 3D printed different composite ratios of HA/β-TCP scaffolds with 8.75 wt% phosphoric acid solution.

(A) Designed scaffolds using Solidworks CAD software. (B) The structural dimensions of the scaffolds. (C) Micro-CT and 3D reconstruction images of the scaffolds. (D) XRD pattern of the scaffolds with different HA/β-TCP ratios.

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Fig 1 Expand

Fig 2.

Bibulous rate of the printed scaffolds (0.6 wt% polyvinyl alcohol + 0.25 wt% Tween 80 (P) and with 8.75 wt% phosphoric acid + 0.25 wt% Tween 80 (H)) with different HA/β-TCP ratios.

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Fig 2 Expand

Table 3.

Dimensional variations of the scaffolds before and after measuring bibulous rate.

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Table 3 Expand

Fig 3.

(A) Mechanical properties test. (B) Fragment of bone scaffolds. (C) A stress–strain curve of the printed scaffolds (polyvinyl alcohol scaffolds (PVA) and phosphoric acid scaffolds (H3PO4)) with different HA/β-TCP ratios. (D) A representation of the compressive stress, corresponding strain and tangent modulus.

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Fig 3 Expand

Table 4.

Mechanical properties of produced BCP scaffolds.

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Table 4 Expand

Fig 4.

Compressive strength of the scaffolds with different porosity.

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Table 5.

Porosity of BCP scaffolds.

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Fig 5.

(A) Comparison of experimental porosity. Design porosity was 50% and is represented by dashed line bars. (B) Comparison of experimental macropore size. Macropore size was 800μm and is represented by dashed line bars.

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Fig 5 Expand

Fig 6.

SEM of 3D fabricating bone scaffolds.

(A) SEM of the phosphoric acid scaffold. (B) SEM of the phosphoric acid scaffold. (C) High magnification (500 ×) images of the red rectangle in B. (D) SEM of the polyvinyl alcohol scaffold. (E) SEM of the polyvinyl alcohol scaffold. (F) High magnification (500 ×) images of the red rectangle in E. In A, and D, red circles indicate design porosity; yellow circles indicate the tiny gap between the powder particles.

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Fig 6 Expand

Fig 7.

The proliferation of BMSCs cultured on the biphasic calcium phosphate scaffolds for 3, 7, and 14 days.

Significantly ($) higher than culture day 3 (p<0.05). *Significantly higher than the scaffolds with H2080, H4060 and H6040 (p<0.05).

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Fig 7 Expand

Fig 8.

A and B depicts the morphology and distribution of the BMSCs attached on the H6040 and the P6040 scaffolds strut surfaces post culture 14 days.

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Fig 8 Expand