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Fig 1.

Graphite cluster model.

(Carbon atoms shown in middle gray, and H atoms shown in light gray).

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Fig 1 Expand

Fig 2.

Optimized geometry structure of oxygen molecule adsorbed on the graphite withdifferent oxygen-containing functional groups.

(Carbon atoms shown in middle gray, oxygen atoms shown in red and H atoms shown in light gray).

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Fig 2 Expand

Table 1.

The main parameters of geometry structure and adsorption energy.

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Table 1 Expand

Table 2.

Mulliken atomic charges.

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Table 2 Expand

Fig 3.

Final configuration of single oxygen atom adsorbed on the surface of graphite.

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Fig 3 Expand

Table 3.

The main parameters of geometry structure and adsorption energy.

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Table 3 Expand

Fig 4.

Final optimized geometry structure of single oxygen atom adsorbed on the graphite with quinone functional groups.

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Fig 4 Expand

Fig 5.

Final optimized geometry structure of oxygen atom adsorbed on the graphite with carbonyl functional groups.

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Fig 5 Expand

Fig 6.

Final optimized geometry structure of single oxygen atom adsorbed on the graphite with hydroxyl functional groups.

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Fig 6 Expand

Fig 7.

Final optimized geometry structure of single oxygen atom adsorbed on the graphite surface with carboxyl functional groups.

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Fig 7 Expand

Table 4.

Sumarize of the main parameters of geometry structure and adsorption energy.

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Table 4 Expand

Table 5.

Mulliken atomic charges.

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Table 5 Expand