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Fig 1.

Effects of MeJA application (250 μmol L-1) on gentiopicroside biosynthesis in Gentiana macrophylla seedlings.

(A). Chromatogram of extraction from seedlings not exposed to MeJA. (B). Chromatogram of extraction from seedlings after 5 d of MeJA treatment. (C). Chromatogram of gentiopicroside standard. (D). Changes over time in gentiopicroside concentrations in treated seedlings relative to levels in untreated control (C) plants.

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Table 1.

Overview of sequencing and assembly.

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Fig 2.

COG classifications of assembled unigenes.

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Fig 3.

GO classification of assembled unigenes.

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Table 2.

Secondary metabolism pathways in Gentiana macrophylla sequencing.

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Fig 4.

KEGG pathway enrichment analysis of DEGs.

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Table 3.

DEGs up-regulated in JA biosynthesis and JA signaling pathway in M5 samples compared with expression in C samples.

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Fig 5.

DEGs involved in alpha-linolenic acid metabolism in M5 samples compared with C samples.

3.1.1.4, secretory phospholipase A2; 1.13.11.12, lipoxygenase; 4.2.1.92, allene oxide synthase; 1.1.1.1, alcohol dehydrogenase; 5.3.99.6, allene oxide cyclase; 1.3.1.42, 12-oxophytodienoic acid reductase; OPCL1, OPC-8:0 CoA ligase 1; ACX, acyl-CoA oxidase; 2.3.1.16, acetyl-CoA acyltransferase 1; 2.1.1.141, jasmonate O-methyltransferase. Green box, putative encoding gene is down-regulated; red boxes, putative encoding genes are up-regulated; blue boxes, some putative encoding genes are up-regulated while others are down-regulated.

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Table 4.

Putative genes that encode enzymes involved in gentiopicroside biosynthesis and DEGs for which expression is altered in response to MeJA treatment.

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Fig 6.

DEGs involved in gentiopicroside biosynthesis pathway in M5 samples compared with C samples.

DXS, 1-deoxy-D-xylulose-5-phosphate synthase; DXR, deoxylulose 5-phosphate reductoisomerase; MCT, 2-C-methyl-D-erythritol 4-phosphate cytidylyltransferase; CMK, 4-(cytidine -5’-diphospho)- 2-C-methyl-D- erythritol kinase; MCS, 2-C-methyl-D-erythritol-2,4- cyclodiphosphate synthase; HDS, 1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate synthase; HDR, 1-hydroxy-2-methyl -2-(E)-butenyl 4-diphosphate reductase; IDI, isopentenyl diphosphate isomerase; AACT, acetyl-CoA C-acetyltransferase; HMGS, 3-hydroxy-3-methylglutaryl-coenzyme A synthase; HMGR, 3-hydroxy-3- methylglutaryl-coenzyme A reductase; MK, mevalonate kinase; PMK, 5-phosphomevelonate kinase; MVD, mevalonate-5-pyrophosphate decarboxylase; GPPS, geranyl diphosphate synthase; GES, geraniol synthase; G10H, geraniol 8-oxidase/geraniol 10-hydroxylase; CPR, cytochrome P450 reductase; 8/10HGO, 8-hydroxygeraniol oxidoreductase; IS, iridoid synthase; IO, iridoid oxidase; 7-DLGT, 7-deoxyloganetic acid glucosyl transferase; 7-DLH, 7-deoxyloganic acid hydroxylase; LAMT, loganic acid O-methyltransferase; SLS, secologanin synthase. Red squares, putative encoding genes are up-regulated; blue squares, putative encoding genes are down-regulated.

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Fig 7.

DEGs involved in glycolysis in M5 samples compared with C samples.

5.4.2.2, phosphoglucomutase; 2.7.1.1, hexokinase; 5.1.3.15, glucose-6-phosphate 1-epimerase; 4.1.2.13, fructose-bisphosphate aldolase; 5.3.1.1, triosephosphate isomerase; 1.2.1.12, glyceraldehyde 3-phosphate dehydrogenase; 2.7.2.3, phosphoglycerate kinase; 5.4.2.12, 2,3-bisphosphoglycerate- independent phosphoglycerate mutase; 4.2.1.11, enolase; 2.7.1.40, pyruvate kinase; 4.1.1.49, phosphoenolpyruvate carboxykinase; 1.2.4.1, pyruvate dehydrogenase E1 component alpha subunit; 4.1.1.1, pyruvate decarboxylase; 2.3.1.12, dihydrolipoamide acetyltransferase; 1.1.1.27, L-lactate dehydrogenase; 1.8.1.4, dihydrolipoamide dehydrogenase; 1.2.1.3, aldehyde dehydrogenase; 1.1.1.1, alcohol dehydrogenase. Green box, putative encoding gene is down-regulated; red boxes, putative encoding genes are up-regulated; blue boxes, some putative encoding genes are up-regulated while others are down-regulated.

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Fig 8.

qRT-PCR validation of 12 unigenes involved in gentiopicroside biosynthesis in G. macrophylla seedlings.

DXS, 1-deoxy-D-xylulose-5-phosphate synthase; DXR, deoxylulose 5-phosphate reductoisomerase; GES, geraniol synthase; G10H, geraniol 8-oxidase/geraniol 10-hydroxylase; 8/10HGO, 8/10-hydroxygeraniol oxidoreductase; HMGR, 3-hydroxy-3-methylglutaryl-coenzyme A reductase; HMGS, 3-hydroxy-3-methylglutaryl-coenzyme A synthase; MVD, mevalonate-5- pyrophosphate decarboxylase; CPR, cytochrome P450 reductase; HDS, 1-hydroxy-2-methyl-2- (E)-butenyl 4-diphosphate synthase; HDR, 1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate reductase.

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