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Fig 1.

Sample compositions and isopleth sections (A: xCu: xLi = 0.5; B: xCu: xSn = 0.5; C: xLi: xSn = 0.5; D: xSn = 0.1; E: xLi = 0.1; F: xCu = 0.1; G: xSn = 0.2; H: xLi = 0.2; I: xCu = 0.2).

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Fig 1 Expand

Table 1.

Heat treatment and quenched phases of Cu-Li-Sn samples at annealing temperatures.

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Table 1 Expand

Table 2.

DTA results of all samples.

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Table 2 Expand

Fig 2.

Isopleth A.

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Fig 2 Expand

Fig 3.

Isopleth B including section from xLi = 0.05–0.20 / T = 184–192°C.

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Fig 3 Expand

Fig 4.

Isopleth C including both sections from xCu = 0–0.18 / T = 300–600°C and xCu = 0.18–0.30 / T = 100–300°C.

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Fig 4 Expand

Fig 5.

Isopleth D including section from xLi = 0–0.10 / T = 300–600°C.

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Fig 5 Expand

Fig 6.

Isopleth E including section from xSn = 0.10–0.30 / T = 400–800°C.

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Fig 6 Expand

Fig 7.

Isopleth F including section from xSn = 0.20–0.40 / T = 400–800°C.

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Fig 7 Expand

Fig 8.

Isopleth G including section from xLi = 0–0.20 / T = 500–800°C.

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Fig 8 Expand

Fig 9.

Isopleth H.

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Fig 9 Expand

Fig 10.

Isopleth I including sections from xSn = 0.20–0.35 / T = 600–800°C and xSn = 0.25–0.40 / T = 400–600°C.

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Fig 10 Expand

Fig 11.

Liquidus projection including section of Li-rich corner.

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Fig 11 Expand

Table 3.

Invariant ternary reactions: Temperatures and reactions in dotted and italic lines are approximated.

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Table 3 Expand

Table 4.

Invariant reactions of the binary subsystems.

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Table 4 Expand

Table 5.

Three-phase equilibria in Cu-Li-Sn directly derived from experiments.

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Table 5 Expand

Fig 12.

Reaction scheme T < 400°C.

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Fig 12 Expand

Fig 13.

Reaction scheme T = 400–600°C.

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Fig 13 Expand

Fig 14.

Reaction scheme T > 600°C.

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Fig 14 Expand