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Fig 1.

Chemical structure of ponatinib (PNT) and Vandetanib (IS).

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Fig 2.

TIC chromatogram of MRM of PNT (5–400 ngmL-1) and IS (100 ngmL-1).

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Fig 3.

MRM mass spectra and the expected fragmentation pathway of (a) PNT and (b) vandetanib (IS).

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Table 1.

Data of back-calculated PNT concentration of the calibration standards from RLMs and plasma matrices.

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Table 2.

Intra-day and inter-day precision and accuracy of the proposed methods.

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Table 3.

Recovery of QC samples for determining the concentration of PNT in plasma and RLMs matrix.

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Table 4.

PNT Stability data and dilution integrity in plasma matrix under different conditions.

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Table 4 Expand

Table 5.

PNT Stability data and dilution integrity in RLMs matrix under different conditions.

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Table 5 Expand

Fig 4.

The metabolic stability profile of PNT after incubation with RLMs.

Metabolic reaction was stopped at different time points.

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Fig 4 Expand