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Fig 1.

Overview of the anhydrosugar cycle and its relevance to the production of biorenewable fuels and chemicals.

Images are from creative commons.

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Table 1.

16S rRNA gene-based identification of soil isolates and population analysis of 16S rRNA gene for five cellobiosan-utilizing bacterial isolates and four levoglucosan-utilizing bacterial isolates based on sequences of Iowa COBS soil microbial community.

Isolates S1, S2, S3, S4, S5, and F6 utilize cellobiosan. Isolates 1, 2, 3 and 4 utilization levogluocsan. OTU: Operational taxonomic unit, here is defined as genes sharing 97% sequence similarity in the COBS dataset. Abundance: the relative abundance of OTU within COBS dataset.

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Fig 2.

Isolation of microbes capable of using cellobiosan as sole carbon source.

(A) Aqueous soil extract, (B) Soil. Pure cultures of S1-S5 and F6. All plates consisted of M9 with 2.0 wt% cellobiosan and were grown at 30°C for 24 hours.

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Fig 3.

Microbial growth on cellobiosan.

(A) Enterobacter DSM16657, (B) our soil isolates on M9 minimal medium with 2.0 wt% cellobiosan at 30°C, 200 rpm for 24 hours. Data is the average of 3 biological replicates, with error bars showing one standard deviation.

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Fig 4.

Growth of our isolates on levoglucosan and cellobiosan.

Growth of isolates in M9 with 2.0 wt% levoglucosan (M9-LG), M9 with 2.0 wt% cellobiosan (M9-C), LB with no supplemental carbon (LB), LB with 2.0 wt% levoglucosan (LB-LG), and LB with 2.0 wt% cellobiosan (LB-C). Note that M9 is a mineral salts media and a supplemental carbon source must be provided to support microbial growth. Thus, M9 with no supplemental carbon is not feasible. Isolates were grown for 24 hours at 30°C, 200 rpm. Data is the average of three biological replicates and error bars indicate the standard deviation. P values were < 0.01 for all organisms in M9-LG versus M9-C and < 0.05 for all organisms in LB-LG vs. LB-C.

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Fig 5.

Phylogenetic analysis.

A maximum likelihood reconstruction of the phylogenetic analysis of 16S rRNA genes of our isolates (blue boxes) and of selected type strains. Isolates are more diverse than previously reported levogluosan-utilizing isolates (red box). The closest relative to isolates by 16S rRNA gene similarity in the RDP database is shown in parentheses.

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Table 2.

Strains within the NCBI nr database sharing similarity to the isolates studied here.

Strains were selected based on their reported ability to utilize levoglucosan. Bacillus horikoshii, Bacillus korlensis 1 and 2, and Bacillus sp 5138, were originally named bacterium levoglucosan 1, 2, 8, and 10, respectively, and were putatively identified in this work (Table 1).

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