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Fig 1.

Structures of oleanolic (A) and ursolic acids (B).

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Table 1.

EC50, CC50 and SI induced by OA, UA, amphotericin B and Miltefosine against L. (L.) amazonensis promastigotes and macrophages.

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Fig 2.

Ultrastructural changes of L. (L.) amazonensis promastigote induced by in vitro treatment with UA.

Images of cultured promastigote forms before (A) and after treatment (B, C, D and E) with UA EC50 were captured by transmission electron microscopy. (N)–Nucleus, (K)–Complex kinetoplast-Mitochondria; red arrow: mitochondrion swelling; white arrow: membrane-containing vacuoles; white asterisk: blebs on nucleus and mitochondria.

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Fig 3.

The mechanism of parasite death was investigated after in vitro treatment with UA.

By flow cytometry the pattern of Annexin V and PI staining was analyzed in non-treated promastigotes (A), UA-treated promastigotes (B) and H2O2-treated promastigotes (C); and it was characterized as “viable cells” in Q1 (Annexin V-/PI-), “early apoptosis stage” in Q2 (Annexin V+/PI-), “late apoptosis stage” in Q3 (Annexin V+/PI+) and “cellular death/necrosis” in Q4 (Annexin V-/PI+). D—Activity of caspase 3/7 was investigated in UA-treated parasites. E—Aspect of nuclear DNA from control parasites (lane 2), UA-treated parasites (lane 3) and H2O2-treated parasites, molecular marker is represented in lane 1; F—JC1 aggregates were analyzed in control, UA—and H2O2—treated parasites.

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Fig 4.

Infection Index (II) of L. (L.) amazonensis-infected peritoneal macrophages submitted to different treatments (A). Peritoneal macrophages were infected with promastigote forms of L. (L.) amazonensis and treated for 24 and 72h with UA or amphotericin B (Amp B– 0.1 μg/mL). Illustration of control infected macrophages (B), infected cells treated with 0.1 μg/mL (C), 1.0 μg/mL (D) and 10.0 μg/mL (E) of UA as well as 0.1 μg/mL of amphotericin B (F) at 24 and 72h. Results are represented by mean and standard deviation of three independent experiments and three replicates per sample. * (p<0.05) indicate significant differences.

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Fig 5.

Nitrite levels were evaluated in supernatant of L. (L.) amazonensis-infected peritoneal macrophages submitted to different treatments.

Peritoneal macrophages were infected with promastigote forms of L. (L.) amazonensis and treated for 24 or 72h with UA or amphotericin B (Amp B– 0.1 μg/mL). Results are represented by mean and standard error of three independent experiments and three replicates per sample. * (p<0.05) indicates significant differences.

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Fig 6.

BALB/c mice were infected with promastigote forms of L. (L.) amazonensis and treated with 1.0 and 2.0 mg/kg of UA or 100.0 mg/kg of Glucantime (Glu).

The development of the disease was monitored for 5 weeks through weekly measurement of lesions. Results are represented by mean and standard error of three independent experiments, containing 5 animals per group. * (p<0.05) indicates significant differences when compared treated groups vs infected, non-treated group.

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Fig 7.

Parasite inhibition after treatment. Footpad lesions of control mice and of mice treated with of UA (1.0 mg/kg or 2.0 mg/kg) or Glucantime (100.0 mg/kg).

Results are represented by mean and standard error of three independent experiments containing five animals per group. * and + (p<0.05) indicate significant differences when compared non-treated vs treated mice and, Glucantime vs UA treated mice, respectively.

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Fig 8.

Histological sections of skin from L. (L.) amazonensis mice submitted or not with UA and amphotericin treatments.

A—Skin histological section of an infected control mice; B—Skin histological section of an infected BALB/c mice treated with UA (1.0mg/kg); C—Skin histological section of an infected BALB/c mice treated with UA (2.0mg/kg); D—Skin histological section of an infected BALB/c mice treated with amphotericin B (5.0mg/kg). Skin sections were staining with hematoxilin & eosin staining and observed under optical microscope at a magnification of 40x.

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