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Fig 1.

Conceptual Diagram.

The conceptual diagram describes OPA-MOF synthesis, and bacterial processing and mineralisation of the structurally incorporated oxalate when applied to soil; plant nutrient release is proposed as a result of the microbially induced structural collapse of the mineral, where N is delivered from pore-residing guest molecule urea and P from the Fe-P octahedral units that form the framework.

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Table 1.

Experimental soil parameters.

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Table 2.

Experimental nutrient applications.

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Table 3.

Nutrients in shoot tissues from high treatment rate.

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Table 4.

Nutrients in grains from high treatment rate.

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Fig 2.

Fertilizer effects on soil nutrients.

Effect of fertilizer treatments on soil concentrations of nitrate (a), ammonium (b), total-N (as calculated sum of nitrate- and ammonium-N; c), Bray-I P (d) and soil pH (e) (in mg/kg—y-axis) over time after application at high rate (equivalent to 120 kg N ha-1). Error bars above individual graphs represent significance between treatments (standard error of means; s.e.m.) at 95% confidence level for each sampling time (weeks 4, 7, 13, 17 and 22).

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