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Fig 1.

Parallel and antiparallel-stranded DNA duplexes depending on pH value (A) and chemical structure of the Watson-Crick and reverse Watson-Crick as well as Hoogsteen base pairs (B).

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Fig 1 Expand

Table 1.

Summary of biophysical properties of D1-D18 duplexes at various buffers pH values.a

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Table 1 Expand

Fig 2.

CD spectra of D1-D18 duplexes at pH 5.0 (black line) and 7.0 (red line).

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Fig 2 Expand

Fig 3.

Time-resolved fluorescence lifetime analysis of the DNA/RNA-LNA (D4) duplex at pH 7.0.

Top panel—donor fluorescence decay in the presence of acceptor (black line) and the instrument response function (IRF, red line); bottom panel—the weighted residuals.

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Fig 3 Expand

Fig 4.

The fluorescence lifetime and normalized fluorescence intensity of selected D1, D3, D7 and D9 duplexes at pH 7.0.

Black line indicates the S1 control probe for D1-D6 duplexes and the S2 control probe for D7-D12 duplexes. Red and blue lines indicate respective duplexes.

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Fig 4 Expand

Fig 5.

Normalized fluorescence intensity of D1-D18 duplexes at pH 7.0 (blue line) and pH 5.0 (red line).

Black line indicates fluorescence of control probe S1 for D1-D6 duplexes, control probe S2 for D7-D12 duplexes as well as control probe S3 for D13-D18 duplexes.

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Fig 5 Expand