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Table 1.

Published literature on the degradation half-life experiments in seawater.

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Table 1 Expand

Table 2.

Experimental details of two degradation experiments investigating herbicide degradation in (1) filtered seawater and (2) unfiltered seawater.

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Table 2 Expand

Fig 1.

Experiment 1 half-life results.

ln(x) concentration of the herbicide mixture: (a) tebuthiuron, (b) ametryn, (c) hexazinone, (d) simazine, (e) atrazine, and (f) diuron over 60 days. SE = Standard error. MC = mercuric chloride treatment.

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Fig 1 Expand

Table 3.

Experiment 1 and 2 half-lives.

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Table 3 Expand

Fig 2.

Experiment 2 half-life results for diuron and atrazine.

ln(x) concentration of individual herbicide treatments: (a) diuron dark 25°C, (b) diuron light 25°C, (c) diuron dark 31°C, (d) atrazine dark 25°C, (e) atrazine light 25°C, and (f) atrazine dark 31°C over 365 days. Dashed lines represent 95% confidence intervals. Half-life reported ± SE.

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Fig 2 Expand

Fig 3.

Experiment 2 half-life results for hexazinone and tebuthiuron.

ln(x) concentration of individual herbicide treatments: (a) hexazinone dark 25°C, (b) hexazinone light 25°C, (c) hexazinone dark 31°C, (d) tebuthiuron dark 25°C, (e) tebuthiuron light 25°C, and (f) tebuthiuron dark 31°C over 365 days. Dashed lines represent 95% confidence intervals. Half-life reported ± SE.

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Fig 3 Expand

Fig 4.

Experiment 2 half-life results for metolachlor and 2,4-D.

ln(x) concentration of individual herbicide treatments: (a) metolachlor dark 25°C, (b) metolachlor light 25°C, (c) metolachlor dark 31°C, (d) 2,4-D dark 25°C, (e) 2,4-D light 25°C, and (f) 2,4-D dark 31°C over 365 days. Dashed lines represent 95% confidence intervals. Half-life reported ± SE.

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Fig 4 Expand

Table 4.

The ratio of half-lives between each treatment from experiment 2.

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Table 4 Expand

Fig 5.

Concentration of metabolites of diuron and atrazine.

Concentrations of individual herbicides including measured metabolites (a) diuron light 25°C, (b) atrazine dark 25°C, (c) atrazine light 25°C, and (d) atrazine dark 31°C, over 365 days. Bars represent ± SE. Note the concentration scales for the parent and metabolite are on opposite sides of each graph.

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Fig 5 Expand