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Table 1.

List of primers used in this study.

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Table 1 Expand

Fig 1.

The effect of tricyclazole on melanization during asexual development.

(A) The generic DHN melanin biosynthetic pathway [15, 24, 43]. Enzymes acting at each step include polyketide synthase (PKS), tetrahydroxynaphthalene reductase (4HNR), trihydroxynaphthalene reductase (3HNR), dehydratase (D), and laccase. Intermediate metabolites including 1,3,6,8-tetrahydroxynaphthalene (1,3,6,8-THN), scytalone, 1,3,8-trihydroxynaphthalene (1,3,8-THN), vermelone, and 1,8-dihydroxynaphthalene (1,8-DHN). (B) At 28°C, T. marneffei F4 colonies appear green as a result of the pigmented conidia. The addition of 30 μg/ml tricyclazole, which inhibits two reductases (4HNR and 3HNR) functioning during DHN melanin synthesis, results in yellow conidiation.

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Fig 2.

Phylogenetic analysis and partial sequence alignment.

(A) Putative fungal MCO sequences from a number of species, including those predicted in T. marneffei, were obtained from Genbank (http://www.ncbi.nlm.nih.gov/protein/) and used to build sequence alignments in CLUSTALW. The alignment was then used to construct a relatedness tree using MEGA 6 software. Phylogenetic relationships of the 55 MCOs were inferred using the Neighbor-Joining method and bootstrap tested (1000 replicates). Branch lengths of the tree are drawn to scale and bootstrap support indicating at the branch sites. Fungal MCOs that share a common ancestry with more than 60% bootstrap value are shaded in gray. Functions are defined at each clade based on characterized function of MCO members. (B) A partial alignment representing the conserved motifs of copper binding sites and L1–L4 signature sequences found in T. marneffei PbrB (PMAA_082060) and its orthologs A. fumigatus Abr2 (AFUA_2G17530) and A. nidulans YA (AN6635). The numbers in front of each sequence indicate the amino acid position of a particular protein. Cu binding motifs are identified above the sequences, numbers including 1, 2, and 3 are type 1 Cu, type 2 Cu, and type 3 Cu. The asterisk indicates the potential proton donor for the reaction intermediates.

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Fig 3.

Expression and localization of PbrB in T. marneffei.

Epifluorescence microscopy of the T. marneffei strain expressing the PbrB::GFP fusion in vegetative cells grown at 37°C (A) or 28°C (B) for 3 days. No GFP fluorescence was noted in either cell type. Epifluorescence microscopy of the T. marneffei conidiophores from the wild type (G681) strain (C) and the strain expressing the PbrB::GFP fusion (D) under bright field and fluorescence optics. The PbrB::GFP fusion is observed as distinct spots (white arrows) in metulae and phialides. Strains were grown on slides at 28°C for 10 days. Microscopic images were captured at 1000X magnification.

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Fig 4.

Localization of PbrB and melanin during conidiation in T. marneffei.

Epifluorescence microscopy after immunostaining using an anti-melanin antibody staining for the wild type control (G681) and the PbrB::GFP fusion strain after growth on slides at 28°C for 10 days. To assess non-specific staining by the rhodamine-labeled secondary antibody (goat anti-mouse IgM antibody), samples were processed without the primary anti-melanin antibody step (labeled as—anti-melanin Ab.). Red fluorescent signals of melanin or melanin-like particles are observed in both wild type and PbrB::GFP fusion strain (+ anti-melanin Ab.). Green fluorescent signals indicate sites of PbrB::GFP proteins. The merged image shows co-localization of PbrB::GFP and melanin-labeled fluorescence. White arrows identify sites of fluorescence signals which melanin-labeled particles co-localize with PbrB::GFP proteins. Microscopic images were captured at 1000X magnification.

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Fig 5.

Macroscopic morphologies of the wild type and mutant T. marneffei strains.

Colonies of the wild type T. marneffei control strain G681, ΔpbrB 1&2 strains, and ΔpbrB pbrB+ 1&2 complemented strains grow on ANM agar at 28°C for 14 days. Conidiation of the ΔpbrB strains is brown compared to the green conidiation of the parental and complemented strains.

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Fig 6.

Germination and growth of the ΔpbrB strain.

Microscopic imaging of the T. marneffei ΔpbrB and ΔpbrB pbrB+ strains grown at 28°C for 24 h to assess germination (A, B) and 7 days to observe conidiophores (C, D). Microscopic images were captured at 200X (A, B) and 400X (C, D) magnification.

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Fig 7.

Vegetative growth rate effects in the ΔpbrB mutant.

Radial growth rates were assessed by measuring colony diameters for the ΔpbrB and ΔpbrB pbrB+ strains growing at 28°C on ANM medium. The line plots the growth rates of ΔpbrB (solid line) and ΔpbrB pbrB+ (dashed line). Error bars present standard error of the mean (SEM). Asterisks indicate significantly difference between strains determined by p-values (p = 0.002 and 0.015). X axis is time and Y axis is the mean colony diameter.

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Fig 8.

Predicted DHN melanin synthesis pathway in T. marneffei.

A consensus biochemical pathway for DHN melanin synthesis based on what is known from other fungal systems is shown [15, 39, 50]. Processing steps of the well-known DHN pathway are presented with dark arrows. PKS, polyketide synthase; 4HNR, tetrahydroxynaphthalene reductase; SD, scytalone dehydratase; 3HNR, trihydroxynaphthalene reductase; VD, vermelone dehydratase; 1,3,6,8-THN, tetrahydroxynaphthalene; 1,3,8-THN, trihydroxynapthalene; 1,8-DHN, dihydroxynaphthalene. Tc, tricyclazole, can inhibit both reductases (4HNR and 3HNR) presented in a model pathway. Distinctive steps described in A. nidulans (An), A. fumigatus (Af), T. marneffei (Tm) are shown with dashed arrows. Asterisks, * and **, refer to data from previous study [22] and this study, respectively.

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