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Figure 1.

Metabolomic profiling of spot urines from SU.VI.MAX2 subjects.

Subjects reported either low or high consumption of coffee, represented by squares and circles respectively. A) One-dimensional OSC-PLS-DA score plot of urinary metabolomes of low and high consumers. B) Loading plot of the OSC-PLS-DA. Circled outlying ions contribute most strongly to the discrimination. C) Model validation assessed by permutation test (n = 100).

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Figure 2.

Chemical structures of some identified discriminants.

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Table 1.

The strongest contributors to the discrimination of low and high coffee consumers.

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Table 1 Expand

Figure 3.

ROC curve analysis of atractyligenin glucuronide and caffeine.

Data for atractyligenin glucuronide are presented in the left-hand column and data for caffeine in the right-hand column. A) Blue curves represent the training set (n = 39 subjects) and pink curves the hold-out set (n = 20 subjects). B) Probabilities of predicted belonging to the high consumer class. Training set, black plots; hold-out set, red plots; filled circles, high consumers; empty circles, low consumers. C) Confusion matrices for the two datasets.

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Figure 4.

ROC curve AUCs for single and combination biomarkers.

Error bars represent 95% confidence intervals. cIP, cyclo(isoleucyl-prolyl); MX, 1-methylxanthine; Tr, trigonelline; Atr, atractyligenin glucuronides; Caf, caffeine.

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