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Figure 1.

Workflow for the study design.

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Figure 2.

Typical HPLC chromatograms.

(A) rhizomes and (B) main roots.

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Figure 3.

Typical chromatograms of rhizome of P. notoginseng.

(a) HPLC-UV, (b) UPLC-PDA and (c) CE-UV, including (1) notoginsenoside R1,(2) ginsenoside Rg1, (3) ginsenoside Re, (9) ginsenoside Rb1, (11) ginsenoside Rd.

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Figure 4.

Typical chromatograms of main roots of P. notoginseng.

(A) HPLC-UV, (B) UPLC-PDA and (C) CE-UV.

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Figure 5.

PCA scores plots of four methods with 95% confidence ellipses.

red dot are rhizomes, black dot are main roots.

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Figure 6.

Dendrograms resulting of cluster analysis.

(A) UPLC data, (B) HPLC data (C) CE and (D) NIR data. The red colored samples represent the rhizomes.

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Figure 7.

PCA scores plots of the testing samples.

The red cross represent the testing rhizome samples. The black cross are mainroot samples.

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Figure 8.

Dendrograms resulting of testing samples.

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Table 1.

The discriminatory variables identified from VIP values.

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Table 2.

The identification of peaks in rhizome and main roots by LC-MSn.

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