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Figure 1.

The structures of Pyl, BocK and AzF.

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Figure 2.

Suppression of amber, opal, and ochre mutations at N134 of sfGFP by their corresponding PylRS-tRNAPyl pairs in the absence and presence of BocK.

(A) Proteins shown in the gel represent their real relative sfGFP expression levels. Lanes 1 and 2 were transformed with pETtrio-PylT(CUA)-PylRS-sfGFP134TAG; lanes 3 and 4 were transformed with pETtrio-PylT(UUA)-PylRS-sfGFP134TAA; lanes 5 and 6 were transformed with pETtrio-PylT(UCA)-PylRS-sfGFP134TGA. ESI-MS spectra of sfGFP expressed in cells (B1) transformed with pETtrio-PylT(CUA)-PylRS-sfGFP134TAG and grown in the presence of 5 mM BocK, (B2) transformed with pETtrio-PylT(UUA)-PylRS-sfGFP134TAA and grown in the presence of 5 mM BocK, (B3) transformed with pETtrio-PylT(UCA)-PylRS-sfGFP134TGA and grown in the absence of BocK, and (B4) transformed with pETtrio-PylT(UCA)-PylRS-sfGFP134TGA and grown in the presence of 5 mM BocK.

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Figure 3.

Suppression of an opal mutation at S2 of sfGFP by the PylRS- pair.

(A) Expression of sfGFP with an opal mutation. Lanes 1 and 2 were transformed with pETtrio-pylT(UCA)-sfGFP134TGA and grown in the absence or presence of 5 mM BocK; lanes 3 and 4 were transformed with pETtrio-pylT(UCA)-sfGFP2TGA and grown in the absence or presence of 5 mM BocK. Each protein shown in the gel represents their real relative expression levels. ESI-MS of sfGFP expressed in cells transformed with pETtrio-pylT(UCA)-sfGFP2TGA and grown in the (B1) absence or (B2) presence of 5 mM BocK.

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Figure 3 Expand

Figure 4.

Suppression of an opal mutation at N134 of sfGFP at different conditions.

(A) Proteins shown in the gel represent their real relative expression levels. Lane 1 was transformed with pET-sfGFP134TGA; lanes 2 and 3 were transformed with pET-pylT(UCA)-sfGFP134TGA and grown in the absence or presence of 5 mM BocK. (B) ESI-MS of sfGFP expressed in cells transformed with pETtrio-sfGFP134TGA.

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Figure 4 Expand

Figure 5.

Suppression of an opal mutation at N134 of sfGFP by different variants.

(A) Proteins shown in the gel represent their real relative expression levels. Lanes 1 and 2 were transformed with pETtrio-pylT(UCA)G73C-sfGFP134TGA and grown in the absence or presence of 5 mM BocK; lanes 3 and 4 were transformed with pETtrio-pylT(UCA)G73A-sfGFP134TGA and grown in the absence or presence of 5 mM BocK; lanes 5 and 6 were transformed with pETtrio-pylT(UCA)G73U-sfGFP134TGA and grown in the absence or presence of 5 mM BocK; lanes 7 and 8 were transformed with pETtrio-pylT(UCA)-sfGFP134TGA and grown in the absence or presence of 5 mM BocK. The ESI-MS analysis of sfGFP expressed in cells transformed with pETtrio-pylT(UCA)G73U-sfGFP134TGA and grown in the (B1) absence or (B2) presence of 5 mM BocK.

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Figure 5 Expand

Figure 6.

Cross recognitions between different anticodons of tRNAPyl and nonsense mutations at N134 of sfGFP.

Cells were transformed with pETtrio-PylT(NNN)-PylRS-sfGFP134N’N’N’ and grown in the presence of 5 mM BocK (NNN and N’N’N’ denote anticodons and codons specified in the figure). Proteins shown in the gel represent their real relative expression levels.

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Figure 7.

Expression of sfGFP in cells transformed with pETtrio-PylT(UUA)-PylRS-sfGFP134TAG.

(A) Cells grown in 2YT medium supplemented without or with BocK. ESI-MS of sfGFP expressed in the (B1) absence or (B2) presence of 5 mM BocK.

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Figure 8.

Expression of sfGFP in cells transformed with pETtrio-PylT(UUA)-PylRS-sfGFP134TAG and pEVOL-AzFRS.

(A)Cells were grown in 2YT medium supplemented with different combinations of NAAs. ESI-MS of sfGFP expressed in the(B1) absence of both AzF and BocK; (B2) presence of 1 mM AzF; (B3) presence of 5 mM BocK; and (B4) presence of both 1 mM AzF and 5 mM BocK.

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Figure 9.

Suppression of an AGG mutation at S2 of sfGFP by.

(A) Expression of sfGFP in cells transformed with pETtrio-pylT(CCU)-sfGFP2AGG and grown in the absence or presence of 5 mM BocK. (B) The ESI-MS analysis of sfGFP expressed in the presence of 5 mM BocK.

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Figure 9 Expand