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Figure 1.

Experimental design and chemical analysis workflow.

(1) pre-conditioning (entrainment) of the culture stock (adaptation to the 12/12-h (light/dark) cycle); (2) incubation of female fruit flies with 13C6-glucose solution; (3) dissection of the anesthetized flies; (4a/4b) preparation of individual eggs for mass spectrometric analysis; (5) mass spectrometry, and (6) data analysis.

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Figure 1 Expand

Figure 2.

Isotopic labeling of ATP and UDP-glucose in single eggs.

(A) MALDI mass spectra obtained from fruit flies following 1, 6, and 19 days of incubation with the 13C6-glucose solution. (B) Reaction scheme of labeling glucose moiety in UDP-glucose with 13C6-glucose.

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Figure 2 Expand

Figure 3.

Progressive incorporation of the 13C-label to UDP-glucose in fruit fly eggs.

The data points were fitted with a sigmoid function: y = 1.013·(1/(1+e(−0.135x+1.792))). During this experiment, the flies were incubated with 13C6-glucose and illuminated with white light (∼ 4000 lux). Note that the sampling intervals (as projected onto the x-axis) are coincidentally not constant.

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Figure 3 Expand

Figure 4.

Influence of temperature (21 vs. 28°C) and illumination (dark vs. light) on the labeling of glucose moiety in UDP-glucose molecules extracted from individual eggs.

Female flies were incubated with 13C6-glucose solution during 24 h. The default conditions were: white light on, ∼4000 lux (in the study involving the change of temperature); temperature, 28°C (in the study involving the change of illumination).

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Figure 5.

Histograms showing the distributions of labeling levels within the eggs obtained from the fruit flies incubated with 13C6-glucose (during 12 h) at different illumination conditions and at different times during the day/night cycle.

ML – flies incubated during day (starting from the morning) at light; MD – flies incubated during day (starting from the morning) at dark; EL – flies incubated during night (starting from the evening) at light; ED – flies incubated during night (starting from the evening) at dark.

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Table 1.

Notation used in this report.

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Table 1 Expand

Figure 6.

Histograms showing differences in the labeling of eggs among flies from the same treatment.

Flies incubated during night (starting from the evening) at dark (ED): arbitrarily selected examples of five single-fly histograms, ordered according to the increasing level of labeling (Fly #1 to #5: top to bottom). All single-fly histograms from this experimental variant are displayed in Figure S9.

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