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Table 1.

KRAS mutations in 300 consecutive samples analyzed by Sanger sequencing and ASLNAqPCR.

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Table 2.

BRAF mutations analysis in 201 consecutive samples analyzed by Sanger sequencing and ASLNAqPCR.

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Table 3.

Primers and beacon probes.

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Figure 1.

Diagram illustrating ASLNAqPCR.

Left side: a single mismatch of the LNA modified primer does not allow PCR amplification. Right side: in case of a perfect match, the Taq polymerase extends the DNA strand and the amplicon is detected by the internal LNA modified beacon probe.

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Table 4.

PCR conditions for Sanger sequencing and ASLNAqPCR.

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Figure 2.

Standard curve titration of ASLNAqPCR for KRAS.

Serial dilution of the KRAS G12V mutated SW620 cell line DNA in wild type DNA. Gray squares correspond to 50%, 20%, 10%, 5%, 1%, 0,1%, 0.01% mutant to wild type DNA ratios (duplicate samples). The titration slope is −3.076, R2 is 0.991 (top right), corresponding to a PCR efficiency of 111.3%.

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Figure 3.

Standard curve titration of ASLNAqPCR for BRAF.

Serial dilution of the BRAF V600E mutated OCUT cell line DNA in wild type DNA. Gray squares correspond to 50%, 20%, 10%, 5%, 1%, 0,1%, 0.01% mutant to wild type DNA ratios (duplicate samples). The titration slope is −2.985, R2 is 0.991 (top right), corresponding to a PCR efficiency of 116.2%.

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Table 5.

Frequence of specific KRAS and BRAF mutations cases analyzed by SSEQ and ASLNAqPCR.

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Table 6.

KRAS mutations in primary colon carcinoma (n = 163) compared with data reported in the literature

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Table 7.

KRAS Pyrosequencing analysis of cases with discordant results between ASLNAqPCR and Sanger sequencing.

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Table 8.

BRAF Pyrosequencing analysis of cases with discordant results between ASLNAqPCR and Sanger sequencing.

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Figure 4.

ASLNAqPCR and corresponding Sanger sequencing of four representative tumor samples analyzed for KRAS mutations.

Sample A is wild type, samples B, C and D are KRAS G12D mutated with varying amounts of tumor vs. non neoplastic cells; assuming that KRAS G12D is heterozygous, quantitation of mutated DNA by ASLNAqPCR (ΔCT method) is consistent with 70% of mutated cells in sample B, 40% of mutated cells in sample C, 4% of mutated cells in sample D; in sample D the KRAS G12D mutation is detected only by the ASLNAQPCR due to its high analytical sensitivity.

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Figure 5.

ASLNAqPCR and corresponding Sanger sequencing of four representative tumor samples analyzed for the BRAF V600E mutation.

Sample A is wild type, samples B, C and D are BRAF V600E mutated with varying amounts of tumor vs. non neoplastic cells; assuming that BRAF V600E is heterozygous, quantitation of mutated DNA by ASLNAqPCR (ΔCT method) is consistent with 75% of mutated cells in sample B, 30% of mutated cells in sample C, 3% of mutated cells in sample D; in sample D the BRAF V600E mutation is detected only by the ASLNAQPCR due to its high analytical sensitivity.

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Figure 6.

KRAS mutations identified by ASLNAqPCR but not by Sanger sequencing. A

, Hematoxylin and Eosin (H&E) stained section (X100) of the area of case 13 of Table 7 (rectal adenocarcinoma treated with preoperative chemo– and radiation therapy) dissected for DNA extraction with a tumor vs. non neoplastic cell ratio of ∼10%, below the analytical sensitivity threshold of Sanger sequencing. B, ASLNAqPCR of case 13 of Table 7 shows a KRAS G12V mutation with a mutated/wild type ratio of 4%, corresponding to 8% mutated cells, assuming that the mutation is heterozygous; this is consistent with the mutation being present in the large majority of neoplastic cells. C, H&E stained section (X100) of the area of the colonic adenocarcinoma case 1 of Table 7, dissected for DNA extraction with a tumor vs. non neoplastic cell ratio of ∼70%. D, ASLNAqPCR of case 1 of Table 7 shows a KRAS G12D mutation with a mutated/wild type ratio of 1.5%, corresponding to 3% mutated cells, assuming that the mutation is heterozygous; this is consistent with a small KRAS G12D mutated subclone corresponding to ∼4% of the neoplastic cells.

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Table 9.

Statistical measures of performance for Sanger sequencing and ASLNAqPCR.

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