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Efficient Synthesis and Anti-Tubercular Activity of a Series of Spirocycles: An Exercise in Open Science

Figure 4

Re-evaluating the route to the 2° amine core 3 (blue).

(A) The attempted route based on the patent literature procedure [12]. The dotted lines represent the additional step (red) required to attempt cyclisation strictly under the patent conditions. (B) The revised strategy: cyclise to give 6 followed by debenzylation to give the 2° amine 3 (blue).

Figure 4

doi: https://doi.org/10.1371/journal.pone.0111782.g004