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Common Hydrogen Bond Interactions in Diverse Phosphoryl Transfer Active Sites

Figure 6

The O3β—Pγ bond length and hyperconjugation increase with decreasing D•••O3β hydrogen bond length in Structure1.

Calculated E(2) energy is of the n(Oγ)→σ*(O3β—Pγ) hyperconjugative interaction. D is the N—H hydrogen bond donor in N-methylacetamide.

Figure 6

doi: https://doi.org/10.1371/journal.pone.0108310.g006