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UV-Light Exposure of Insulin: Pharmaceutical Implications upon Covalent Insulin Dityrosine Dimerization and Disulphide Bond Photolysis

Figure 1

Molecular mechanisms of dityrosine cross-linking (Cortho-Cortho). (

A) Reaction mechanism for the formation of dityrosine. (B) Intermolecular dityrosine cross-linking in proteins.

Figure 1

doi: https://doi.org/10.1371/journal.pone.0050733.g001