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Table 1.

Motor oils used in the study.

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Figure 1.

Schematic of the experimental set-up.

PC: personal computer; Filter: 355 nm long-pass filter; ICCD: intensified charge-coupled device; THG: third harmonic generator output at 355 nm.

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Figure 1 Expand

Figure 2.

Normalized steady-state fluorescence spectra of motor oils, including, Shell 5W-40, Shell 15W-40, Mobil 5W-30, Mobil 5W-40, Mobil 0W-40, Mobil 20W-40, Castrol 5W-40, Prestone 5W-40, GreatWall 10W-50, under 355 nm laser pulse excitation.

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Figure 3.

LIF spectra at specific time gates (including 5 ns, 20 ns, 35 ns, 50 ns, 65 ns, 75 ns).

(a) Mobil 0W-40, (b) Mobil 5W-30, (c) Mobil 5W-40, (d) Mobil 20W-40, (e) Shell 5W-40, (f) Shell 15W-40, (g) Castrol 5W-40, (h) Prestone 5W-40, and (i) GreatWall 10W-50. The normalized fluorescence intensity (y-axis) and the wavelength (x-axis) are used as axes. The wavelength range is 360 nm to 575 nm. The integration time is set to 5 ns.

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Figure 4.

CDTRFIs of (a) Mobil 0W-40, (b) Mobil 5W-30, (c) Mobil 5W-40, (d) Mobil 20W-40, (e) Shell 5W-40, (f) Shell 15W-40, (g) Castrol 5W-40, (h) Prestone 5W-40, and (i) GreatWall 10W-50.

The fluorescence wavelength (y-axis) and the detection time (x-axis) are used as axes. The wavelength range is 360 nm to 560 nm, and the time range is 75 ns with an excitation wavelength of 355 nm. The gate width of the ICCD is set to 5 ns.

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Figure 4 Expand